The gas-phase decomposition of di-terf-butyl peroxide, (CH3)3COOC(CH3)3, is first order in the temperature range 110°C to 280°C with a first-order rate coefficient k = 3.2 X 1016 exp[—(164 kJ moV1/RT)] s_1.
a. What are the values of ∆H‡ and ∆S‡ for this reaction at 110°C?
b. Give a brief interpretation of the value of ∆S‡.
c. At what temperature will the reaction occur ten times faster than at 110°C?
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