Problem

Use the shorthand notation (page 450) to describe the cells in Problem. Each cell is suppl...

Use the shorthand notation (page 450) to describe the cells in Problem. Each cell is supplied with a salt bridge to provide electrical contact between the solutions in the two cell compartments.

Problem Calculate the potential of the following two half-cells that are connected by a salt bridge:

*(a) a galvanic cell consisting of a lead electrode (right electrode) immersed in 0.0220 M Pb2+ and a zinc electrode in contact with 0.1200 M Zn2+.

(b) a galvanic cell with two platinum electrodes, the one on the left immersed in a solution that is 0.0445 M in Fe3+ and 0.0890 M in Fe2+, the one on the right in a solution that is 0.00300 M in Fe(CN)64- and 0.1564 M in Fe(CN)63-.

*(c) a galvanic cell consisting of a standard hydrogen electrode on the left and a platinum electrode immersed in a solution that is 3.50 × 10-3 M in TiO2+, 0.07000 M in Ti3+, and buffered to a pH of 3.00.

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Solutions For Problems in Chapter 19