If you start with 0.1000 M solutions and the firstnamed species is the titrant, what will...

If you start with 0.1000 M solutions and the firstnamed species is the titrant, what will be the concentration of each reactant and product at the equivalence point of titrations (a), (c), (f), and (g) in Problem? Assume that there is no change in [H+] during the titration.

Problem

Generate equilibrium constant expressions for the following reactions. Calculate numerical values for Keq.

*(a) Fe3+ + V2+ ⇌ Fe2+ + V3+

(b) Fe(CN)+3- + Cr2+ ⇌ Fe(CN)64- + Cr3+

*(c) 2V(OH)4+ + U4+ ⇌ 2VO2+ + UO22+ +4H2O

(d) Tl3+ + 2Fe2+ ⇌ Tl+ + 2Fe3+

*(e) 2Ce4+ + H3AsO3 + H2O ⇌ 2Ce3+ +H3AsO4 + 2H+ (1 M HClO4)

(f) 2V(OH)4+ + H2SO3 ⇌ SO42- + 2VO2+ + 5H2O

*(g) VO2+ + V2+ + 2H+⇌ 2V3+ + H2O

(h) TiO2+ + Ti2+ + 2H+⇌ 2Ti3+ + H2O