Problem

Generate equilibrium constant expressions for the following reactions. Calculate numerical...

Generate equilibrium constant expressions for the following reactions. Calculate numerical values for Keq.

*(a) Fe3+ + V2+ ⇌ Fe2+ + V3+

(b) Fe(CN)+3- + Cr2+ ⇌ Fe(CN)64- + Cr3+

*(c) 2V(OH)4+ + U4+ ⇌ 2VO2+ + UO22+ +4H2O

(d) Tl3+ + 2Fe2+ ⇌ Tl+ + 2Fe3+

*(e) 2Ce4+ + H3AsO3 + H2O ⇌ 2Ce3+ +H3AsO4 + 2H+ (1 M HClO4)

(f) 2V(OH)4+ + H2SO3 ⇌ SO42- + 2VO2+ + 5H2O

*(g) VO2+ + V2+ + 2H+⇌ 2V3+ + H2O

(h) TiO2+ + Ti2+ + 2H+⇌ 2Ti3+ + H2O

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Solutions For Problems in Chapter 19