Problem

Each of the following reactions has been carried out under conditions such that disubstitu...

Each of the following reactions has been carried out under conditions such that disubstitution or trisubstitution occurred. Identify the principal organic product in each case.

(a) Nitration of p-chlorobenzoic acid (dinitration)


(b) Bromination of aniline (tribromination)


(c) Bromination of o-aminoacetophenone (dibromination)


(d) Nitration of benzoic acid (dinitration)


(e) Bromination of p-nitrophenol (dibromination)


(f) Reaction of biphenyl with tert-butyl chloride and iron(III) chloride (dialkylation)


(g) Sulfonation of phenol (disulfonation)

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