Problem

Use the data in Table 8.5 and the following data: S—S distance in to answer the followi...

Use the data in Table 8.5 and the following data: S—S distance in to answer the following questions: (a) Predict the bond length in a S—N single bond. (b) Predict the bond length in a 5-0 single bond. (c) Why is the S-O bond length in SO2 considerably shorter than your predicted value for the S-0 single bond? (d) When elemental sulfur, S8, is carefully oxidized, a compound S8O is formed, in which one of the sulfur atoms in the S8 ring is bonded to an oxygen atom. The S—O bond length in this compound is 1.48 In light of this information, write Lewis structures that can account for the observed S-O bond length. Does the sulfur bearing the oxygen in this compound obey the octet rule?

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