Homework Answers
(a) A chemical reaction that can convert cis-alkene to trans-alkene is shown below:
The essential condition for this reaction is the presence of heat or sunlight.
(B) The following shows the switching of regiochemistry of an alkyl halide.
Here the reagents which are
used in the chemical reaction are alcoholic KOH and HBr.
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Propose chemical reactions which accomplish the objectives shown below. Specify reagents, essential conditions, and catalysts (10...
2) Propose chemical reactions which accomplish the objectives shown below. Specify reagents, essential conditions, and catalysts...
2) Propose chemical reactions which accomplish the objectives shown below. Specify reagents, essential conditions, and catalysts (10 points). a. Convert a cis-alkene to the corresponding trans-alkene. b. Switch the regiochemistry of an alkyl halide (example: convert 1-bromopentane into 2- bromopentane)
please help me with organic chemistry! i swear we havent talked about any of this in...
please help me with organic chemistry! i swear we havent
talked about any of this in class.
1) Compounds A, B, and have the same molecular formula. C.H. They all react with H/PtO2 to give the same compound. The reaction of A or B with H2O/HSO, or with BH-THF, followed by treatment with a basic solution of hydrogen peroxide, gives the same compound, namely D. The reaction of with H2O/H2SO4 also gives D. However, the reaction of C with BH-THF,...
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the a...
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the alkyl halide which would give only the alkene shown by way of an E2 elimination (one alkyl halide for each alkene): 8. (10 - extra credit) (a) (6) Propose a 2-4 step mechanism to explain this conversion. (b) (4) Draw a reasonable reaction coordinate diagram for this process.
1. (5 points) Required Reagents. For each of these reactions: Draw the structure named as the...
1. (5 points) Required Reagents. For each of these reactions: Draw the structure named as the target molecule in each of these reactions. Then draw a specific substance's structure that fits the description of the organic starting material that could be converted to each target. Finally, write the reagents needed to make the conversion above/below the arrow. Be sure to carefully show the order of the addition of various reagents, if they need to be added as separate steps, and...
2. Provide the reagents/conditions required to accomplish each of the transformations (A-C) below. If a reaction...
2. Provide the reagents/conditions required to accomplish each of the transformations (A-C) below. If a reaction consists of two steps, be sure to show this: 6 points. 3. Draw the starting materials (A and B) required to obtain the products shown below, using the reagents and conditions provided: 6 points. 1. HB(sia), THE 2. H2O2, NaOH, H20 produces 1.03 both products 2.(CH3)2S HgSO4 H2SO4, H20
How to solve alkene and alkyne reactions - Merdanym i Act antalyzod Hrdian ca Come Lazarmistry...
How to solve alkene and alkyne reactions
- Merdanym i Act antalyzod Hrdian ca Come Lazarmistry I V WORKSHOP #9 Alkenes, Alkynes, Reactions 1. Give a reasonable mechanism for the following reaction. Clearly show intermediates and show the movement of electron pairs with curved arrows. all сна H20. (H2SO4) H₃C CH₂ нас он H3CX сна 2. The addition of HBr to 2-methylpropene can, in principle, give either 1-bromo-2- methylpropane or 2-bromo-2-methylpropane. In reality, only the latter is formed. Show mechanisms...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction below: (draw curved arrows, intermediates, and resonance structures if necessary. NO NEED FOR TRANSITION STATES! CH CH CH CH Br Heat CH,CH,OH OCH.CH Mechanism.14 points) Mechanism 2 points) Mechanism.3 14 points) 5. [14 pts] Provide the major products of reacting the alkene shown in the middle of the scheme below with all the reagents independently. Draw the products' structures in the corresponding table below...
Which solvent(s) listed below would be satisfactory in Snl reactions? 0 o Н;С CH; DMSO H3C...
Which solvent(s) listed below would be satisfactory in Snl reactions? 0 o Н;С CH; DMSO H3C Н;С CH3CH2OH H DMF I II III a. I only b. II only c. III only d. I and II Oe. I and III f. II and III Og. All of the above What two products are expected in the following reaction? CH3 HBT H H BI CH CH; CH BI H Br I II III H Br Br H CH; CH IV V...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
need help with the boxed bullet point. writing the chemical reaction scheme for the experiment. Synthesis of an A...
need help with the boxed bullet point. writing the chemical
reaction scheme for the experiment.
Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part I Pre-lab Assignment for Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part 1 1. From The Organic Chem Lab Survival Manual ( edition) by Zubrick • Review pages 201-204: Standard Reflux. • Review pages 127-140: Extraction • Review pages 164-189: Distillation, Simple Distillation. The Distillation Example, and The Distillation Mistake. 2. Read this...
2) Propose chemical reactions which accomplish the objectives shown below. Specify reagents, essential conditions, and catalysts (10 points). a. Convert a cis-alkene to the corresponding trans-alkene. b. Switch the regiochemistry of an alkyl halide (example: convert 1-bromopentane into 2- bromopentane)
please help me with organic chemistry! i swear we havent
talked about any of this in class.
1) Compounds A, B, and have the same molecular formula. C.H. They all react with H/PtO2 to give the same compound. The reaction of A or B with H2O/HSO, or with BH-THF, followed by treatment with a basic solution of hydrogen peroxide, gives the same compound, namely D. The reaction of with H2O/H2SO4 also gives D. However, the reaction of C with BH-THF,...
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the alkyl halide which would give only the alkene shown by way of an E2 elimination (one alkyl halide for each alkene): 8. (10 - extra credit) (a) (6) Propose a 2-4 step mechanism to explain this conversion. (b) (4) Draw a reasonable reaction coordinate diagram for this process.
1. (5 points) Required Reagents. For each of these reactions: Draw the structure named as the target molecule in each of these reactions. Then draw a specific substance's structure that fits the description of the organic starting material that could be converted to each target. Finally, write the reagents needed to make the conversion above/below the arrow. Be sure to carefully show the order of the addition of various reagents, if they need to be added as separate steps, and...
2. Provide the reagents/conditions required to accomplish each of the transformations (A-C) below. If a reaction consists of two steps, be sure to show this: 6 points. 3. Draw the starting materials (A and B) required to obtain the products shown below, using the reagents and conditions provided: 6 points. 1. HB(sia), THE 2. H2O2, NaOH, H20 produces 1.03 both products 2.(CH3)2S HgSO4 H2SO4, H20
How to solve alkene and alkyne reactions
- Merdanym i Act antalyzod Hrdian ca Come Lazarmistry I V WORKSHOP #9 Alkenes, Alkynes, Reactions 1. Give a reasonable mechanism for the following reaction. Clearly show intermediates and show the movement of electron pairs with curved arrows. all сна H20. (H2SO4) H₃C CH₂ нас он H3CX сна 2. The addition of HBr to 2-methylpropene can, in principle, give either 1-bromo-2- methylpropane or 2-bromo-2-methylpropane. In reality, only the latter is formed. Show mechanisms...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction below: (draw curved arrows, intermediates, and resonance structures if necessary. NO NEED FOR TRANSITION STATES! CH CH CH CH Br Heat CH,CH,OH OCH.CH Mechanism.14 points) Mechanism 2 points) Mechanism.3 14 points) 5. [14 pts] Provide the major products of reacting the alkene shown in the middle of the scheme below with all the reagents independently. Draw the products' structures in the corresponding table below...
Which solvent(s) listed below would be satisfactory in Snl reactions? 0 o Н;С CH; DMSO H3C Н;С CH3CH2OH H DMF I II III a. I only b. II only c. III only d. I and II Oe. I and III f. II and III Og. All of the above What two products are expected in the following reaction? CH3 HBT H H BI CH CH; CH BI H Br I II III H Br Br H CH; CH IV V...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
need help with the boxed bullet point. writing the chemical
reaction scheme for the experiment.
Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part I Pre-lab Assignment for Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction, Part 1 1. From The Organic Chem Lab Survival Manual ( edition) by Zubrick • Review pages 201-204: Standard Reflux. • Review pages 127-140: Extraction • Review pages 164-189: Distillation, Simple Distillation. The Distillation Example, and The Distillation Mistake. 2. Read this...
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