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Another lab, similar to yours, had the following results, with the reference +2 Ni (1M)+2e Ni. half-cell being: The results o
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Answer #1

1) Most positive to most negative: Au3+/Au, Fe3+/Fe2+, Fe3+/Fe, Ni2+/Ni, Cr3+/Cr, Al3+/Al, Ba2+/Ba

Explanation: The order of the electrode potentials in the same order: 1.498, 0.771, -0.037, -0.257, -0.744, -1.662, -2.912 V

2) Combination (i).

Oxidation 1/2 reaction: Fe2+(aq) ----> Fe3+(aq) + e-

Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)

Total net ionic equation: 3Fe2+(aq) + Au3+(aq) ----> 3Fe3+(aq) + Au(s)

Eocell = EoAu3+/Au - EoFe3+/Fe2+= 1.498 - 0.771 = 0.727 V

Combination (ii).

Oxidation 1/2 reaction: Fe(s) ---> Fe3+(aq) + 3e-

Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)

Total net ionic equation: Fe(s) + Au3+(aq) ----> Fe3+(aq) + Au(s)

Eocell = EoAu3+/Au - EoFe3+/Fe= 1.498 - (-0.037) = 1.535 V

Combination (iii).

Oxidation 1/2 reaction: Ni(s) ---> Ni2+(aq) + 2e-

Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)

Total net ionic equation: 3Ni(s) + 2Au3+(aq) ----> 3Ni2+(aq) + 2Au(s)

Eocell = EoAu3+/Au - EoNi2+/Ni= 1.498 - (-0.257) = 1.755 V

Combination (iv).

Oxidation 1/2 reaction: Cr(s) ---> Cr3+(aq) + 3e-

Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)

Total net ionic equation: Cr(s) + Au3+(aq) ----> Cr3+(aq) + Au(s)

Eocell = EoAu3+/Au - EoCr3+/Cr= 1.498 - (-0.744) = 2.242 V

Combination (v).

Oxidation 1/2 reaction: Al(s) ---> Al3+(aq) + 3e-

Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)

Total net ionic equation: Al(s) + Au3+(aq) ----> Al3+(aq) + Au(s)

Eocell = EoAu3+/Au - EoAl3+/Al= 1.498 - (-1.662) = 3.16 V

Combination (vi).

Oxidation 1/2 reaction: Ba(s) ---> Ba2+(aq) + 2e-

Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)

Total net ionic equation: 3Ba(s) + 2Au3+(aq) ----> 3Ba2+(aq) + 2Au(s)

Eocell = EoAu3+/Au - EoBa2+/Ba= 1.498 - (-2.912) = 4.41 V

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