1) Most positive to most negative: Au3+/Au, Fe3+/Fe2+, Fe3+/Fe, Ni2+/Ni, Cr3+/Cr, Al3+/Al, Ba2+/Ba
Explanation: The order of the electrode potentials in the same order: 1.498, 0.771, -0.037, -0.257, -0.744, -1.662, -2.912 V
2) Combination (i).
Oxidation 1/2 reaction: Fe2+(aq) ----> Fe3+(aq) + e-
Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)
Total net ionic equation: 3Fe2+(aq) + Au3+(aq) ----> 3Fe3+(aq) + Au(s)
Eocell = EoAu3+/Au - EoFe3+/Fe2+= 1.498 - 0.771 = 0.727 V
Combination (ii).
Oxidation 1/2 reaction: Fe(s) ---> Fe3+(aq) + 3e-
Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)
Total net ionic equation: Fe(s) + Au3+(aq) ----> Fe3+(aq) + Au(s)
Eocell = EoAu3+/Au - EoFe3+/Fe= 1.498 - (-0.037) = 1.535 V
Combination (iii).
Oxidation 1/2 reaction: Ni(s) ---> Ni2+(aq) + 2e-
Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)
Total net ionic equation: 3Ni(s) + 2Au3+(aq) ----> 3Ni2+(aq) + 2Au(s)
Eocell = EoAu3+/Au - EoNi2+/Ni= 1.498 - (-0.257) = 1.755 V
Combination (iv).
Oxidation 1/2 reaction: Cr(s) ---> Cr3+(aq) + 3e-
Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)
Total net ionic equation: Cr(s) + Au3+(aq) ----> Cr3+(aq) + Au(s)
Eocell = EoAu3+/Au - EoCr3+/Cr= 1.498 - (-0.744) = 2.242 V
Combination (v).
Oxidation 1/2 reaction: Al(s) ---> Al3+(aq) + 3e-
Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)
Total net ionic equation: Al(s) + Au3+(aq) ----> Al3+(aq) + Au(s)
Eocell = EoAu3+/Au - EoAl3+/Al= 1.498 - (-1.662) = 3.16 V
Combination (vi).
Oxidation 1/2 reaction: Ba(s) ---> Ba2+(aq) + 2e-
Reduction 1/2 reaction: Au3+(aq) + 3e- ----> Au(s)
Total net ionic equation: 3Ba(s) + 2Au3+(aq) ----> 3Ba2+(aq) + 2Au(s)
Eocell = EoAu3+/Au - EoBa2+/Ba= 1.498 - (-2.912) = 4.41 V
Another lab, similar to yours, had the following results, with the reference +2 Ni (1M)+2e Ni....
Another lab, similar to yours, had the following results, with the reference half-cell being: Nit2(1M) + 2e → Ni. The results obtained, with each half-cell combined, at 20.00 °C, were: + 1.203 v + - 1.206 v Alt + 36 → Al Aut? + 3€ → Au Bat2 + 2e → Ba or +3 + 36 → or $ + +2.017 v $ + +0.456 v $ + - 0.924 v Fe +3 + 36 Fe -0.198 v Ni+21 x...
use tabulated standard electrode potential to calculate the standard cell potential for the reaction occurring in an electrochemical cell at 25 C. (The equation is balanced.) 3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq) Express your answer to two significant figures and include the appropriate units. em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
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please answer all wueston Question 33 (3 points) (33) For a galvanic cell notation: (-) Ni /Ni2+ (aq) // Au3+ (aq) / Au (+), The electrode potentials: Eº (Ni2+/ Ni) = -0.257 V, E ° (AU3+ / Au ) = 1.498 V. The cell potential Eºcell (a) 1.241 V (b) - 1.755 V O (0) 1.755 V (d) 1.498 Why Question 35 (3 points) (35) For galvanic cell: (-) Cr/ Cr3+ (aq) / Cu2+ (aq) / Cu(+), the correct half...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
I need help with questione 1-12 and discussion question 1 and 2. The previous pictures help determine the chart. Please Show Work thank you so much An oxidation half-reaction is characterized by electrons appearing on the product side. The oxidation of aluminum for instance would be represented thusly: Al(s) → Al3+ + 3e- (1) An reduction half-reaction is characterized by electrons appearing on the reactant side. The reduction of ferrous iron for instance would be represented thusly: Fe2+ + 2e...
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