a. What is the energy difference between the axial and the equatorial conformation of: methyl 5.75...
need the answer to the question:
calculate the difference in energy between the axial and equatorial
conformations.
VII. Calculations of the Conformations of Substituted Cyclohexanes In this exercise, you will examine the conformational equilibrium between axial and equatorial methylcyclohexane. Begin by drawing a methylcyclohexane using ChemDraw. Don't forget about the rings shown at the bottom of the toolbar. Chem3D will automatically put the methyl group in the low energy equatorial conformation. Minimize the energy using the calculations) menu. Select MM2...
References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, fir calculate Keaq, and then use this value to find the percentage.) CH3 CH3 Answers: a. The energy difference is 4 b. In the more...
Two methyl groups Distance between methyl carbons 0 1,3-diaxial 1,3-diequatorial 1,3-equatorial/axial 3.410A 5.038 A 4 569 A Cis or trans? Energy Relative energy (kcal/mol) (cis) 41.96 /moll (cis) 20.72 kJ/mol ccis) 26.68 kJ/mol Complete this sentence based on your data in the table above: The_(more/fewer)_ axial methyl groups, the (greater/lesser) the energy of the molecule.
How would you draw the most stable conformation of cis-1-ethyl-2-methylcyclohexane? Axial ethyl group on C-1, Axial methyl group on C-2 Axial ethyl group on C-1, Equatorial methyl group on C-2 Equatorial ethyl group on C-1, Axial methyl group on C-2 Equatorial ethyl group on C-1, Equatorial methyl group on C-2 Choices b and care both correct O Choices a and d are both correct Submit Answer Tries 0/1 How would you draw the most stable conformation of trans-1,4-dimethylcyclohexane? Axial methyl...
How would you draw the most stable conformation of
trans-1-ethyl-3-methylcyclohexane?
Axial ethyl group on C-1, Axial methyl group on C-3
Axial ethyl group on C-1, Equatorial methyl group on C-3
Equatorial ethyl group on C-1, Axial methyl group on C-3
Equatorial ethyl group on C-1, Equatorial methyl group on C-3
Choices b and c are both correct
Choices a and d are both correct
How would you draw the most stable conformation of
trans-1-chloro-2-fluorocyclohexane?
Axial chlorine on C-1, Axial fluorine...
How would you draw the most stable conformation of trans-1-tert-butyl-4-isopropylcyclohexane? Axial tert-butyl group on C-1, Axial isopropyl group on C-4 Axial tert-butyl group on C-1, Equatorial isopropyl group on C-4 Equatorial tert-butyl group on C-1, Axial isopropyl group on C-4 Equatorial tert-butyl group on C-1, Equatorial isopropyl group on C-4 Choices b and c are both correct Choices a and d are both correct تسليم الجواب Tries 0/1 How would you draw the most stable conformation of trans-1,3-cyclohexanediol? Axial hydroxyl...
How would you draw the most stable conformation of trans-1-bromo-4-fluorocyclohexane? O Axial bromine on C-1, Axial fluorine on C-4 O Axial bromine on C-1, Equatorial fluorine on C-4 O Equatorial bromine on C-1, Axial fluorine on C-4 O Equatorial bromine on C-1, Equatorial fluorine on C-4 O Choices b and care both correct O Choices a and d are both correct Submit Answer Tries 0/1 How would you draw the most stable conformation of cis-1,4-dimethylcyclohexane? O Axial methyl group on...
How would you draw the most stable conformation of trans-1-chloro-2-fluorocyclohexane? Axial chlorine on C-1, Axial fluorine on C-2 Axial chlorine on C-1, Equatorial fluorine on C-2 Equatorial chlorine on C-1, Axial fluorine on C-2 Equatorial chlorine on C-1, Equatorial fluorine on C-2 Choices b and c are both correct Choices a and d are both correct Submit Answer Tries 0/1 How would you draw the most stable conformation of cis-1-ethyl-4-methylcyclohexane? Axial ethyl group on C-1, Axial methyl group on C-4...
Determine the conformational preferences (axial or equatorial) for the two indicated groups in the lowest energy ring flip of the molecule below. A - equatorial, B - equatorial A-equatorial, B-axial A - axial. B- equatorial A-axial, B-axial Which of the following molecules are chiral? A only B and D only D only A B and D What is the relationship between molecules A and B? They are enantiomers They are diastereomers They are the same They are constitutional isomers
How would you draw the most stable conformation of trans-1-chloro-4-fluorocyclohexane? Axial chlorine on C-1, Axial fluorine on C-4 Axial chlorine on C-1, Equatorial fluorine on C-4 Equatorial chlorine on C-1, Axial fluorine on C-4 Equatorial chlorine on C-1, Equatorial fluorine on C-4 Choices b and c are both correct Choices a and d are both correct Enviar Respuesta Tries 0/1 How would you draw the most stable conformation of cis-1-tert-butyl-3-methylcyclohexane? Axial tert-butyl group on C-1, Axial methyl group on C-3...