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Hi. can some one please explain me the solution for this question. the correct answer is E. thanks

Consider the following equation. Relevant standard reduction potentials are given in Q8. 9. 2Ag Pb2Ag + Pb Which of the follo

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Answer #1

from data table:

Eo(Pb2+/Pb(s)) = -0.126 V

Eo(Ag+/Ag(s)) = 0.7996 V

As per given reaction/cell notation,

cathode is (Ag+/Ag(s))

anode is (Pb2+/Pb(s))

Eocell = Eocathode - Eoanode

= (0.7996) - (-0.126)

= 0.9256 V

here, number of electrons being transferred, n = 2

Eo = (2.303*R*T)/(n*F) log Kc

At 25 oC or 298 K, R*T/F = 0.0592

So, Eo = (0.0592/n)*log Kc

0.9256 = (0.0592/2)*log Kc

log Kc = 31.2703

Kc = 1.9*10^31

Answer: e

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