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d) Product of part (c) with lithium aluminum hydride; then H,0 (e) Product of part (c)...
Draw the structure of the major product formed in the reaction of t-butylcyclohexanone and lithium aluminum hydride. Draw the major product formed in the reaction of t-butylcyclohexanone and lithium tri-sec-butylborohydride.
5. Each of the following reactions has been reported in the chemical literature. Predict the product in each case, showing stereochemistry where appropriate. (3x2-6] HC XH H,SO CH, heat 1. B He diglyme 2. H.O. HO CHCCH-CH=CHCHCCH- 1. LiAlH4, diethyl ether 2. H20 (c)
After SB HW1 for Org Chem II. Part 1 (out of 3) 1. Write chemical equation, showing all necessary reagents, for the preparation of 3-pentanol by reducing a ketone. 2. Which of the isomeric C5H120 alcohols can be prepared by lithium aluminum hydride reduction of a. An aldehyde b. A ketone c. A carboxylic acid 3. Write chemical equation, showing all necessary reagents, for the preparation of 3-pentanol using Grignard reagent. 4. Provide the structure of the product: OH on.o...
2. Write the chemical formulas for the following: b. aluminum a. copper c. hydrochloric acid e. copper(II) chloride g. sodium hydroxide i. hydrogen k. carbon dioxide m. calcium carbonate o. aluminum chloride q. calcium chloride d. magnesium sulfate – f. sodium bicarbonate h. methane j. sodium chloride 1. oxygen n. magnesium hydroxide p. sodium carbonate — r. water t. carbon monoxide S. sodium v. iron u. sulfur w.iron (II) sulfide y. sulfuric acid x. magnesium chloride z. sodium sulfate 3....
Give the major organic product(s) of the reactions of l-methyl-2-deuteriocyclohexene (D = "H) with the reagents given. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal quantities. CHE 1-methyl-2-deuteriocyclohexene (a) (1) BH, THF: (2) H:03, NaOH, H:0 (b) HBr, AIBN (c) Br, H:0 Give the major organic product(s) of the reactions shown below. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal...
Predict the major product for the following reactions (a) Cl2 AICI (b) H2SO4 ОН (c) COOH CH3CH2I AICI3 (d) NaCN Br (e) O2N. ,NO2 NaSCH3 (f) ОН (g) Cl. 1. KMnO4/NaOH 2. HC
1. (20 pts) Write the structure of the product of each step of these reactions. Be careful to consider if rearrangements occur and if stereoisomers are formed (if so, write the stereo- isomers). HBr Нао 95°C H2 Н2о Lindlar cat. H2SO4 (cat) Na 1) BH3:THF NH3 2) H202, H20, NaOH КОН Н2 Br Pd-C
Question 44 (a,b,d,f,i) and 46 (a,c,e,f) please, I don't understand. Give the expected major product of the reaction of propyne with each of the following reagents. (a) D_2, Pd-CaCO_3, Pb(O_2CCH)_2, quinoline: (b) Na, ND_3: (c) 1 equivalent HI: (d) 2 equivalents HI: (e) 1 equivalent Br_2: (f) 1 equivalent ICl: (g) 2 equivalent ICl: (h) H_2O, HgSO_4, H_2SO_4: (i) dicyclohexylborane, then NaOH, H_2O_2 What are the products of the reactions of dicyclohexylethyne with the reagents in Problem 44? Write the...
U. Amphoteric Behavior of Aluminum Hydroxide B. Test for basic behavior. Describe what happened when HCl was added. # dissolved C. Test for acidic behavior. Describe what happened when NaOH was added. Dident dissole i continued to precipitate. 1. QUESTIONS: Which metals are more reactive - alkali metals (Group IA) or alkaline earth metals (Group ILA)? How do you know? 2. Based on your observations regarding Group IIA metals (calcium and magnesium), which Group IIA metal would you expect to...
1. Provide the missing starting material, reagents, or major organic product for each of the following reactions. (No more than two steps are required in any case where we ask you to fill in reagents.) 1. Mgo, Et20 2. H20 a) Cl b) MgBr OH , Et20 2. H* workup c) OH d) NaOH (cat.) e) OH NaBH4, CeCl3, MeOH