The dissolving of CaCl2 in water is product-favored, but the temperature of the water gets colder during the process. What would be the signs for ΔG, ΔH and ΔS during this process?
CaCl2(s) ---> Ca+2(aq) + 2Cl-1(aq)
ΔG = (+) ΔH = (+) ΔS = (-) |
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ΔG = (-) ΔH = (-) ΔS = (+) |
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ΔG = (-) ΔH = (+) ΔS = (-) |
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ΔG = (-) ΔH = (+) ΔS = (+) |
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ΔG = (+) ΔH = (+) ΔS = (+) |
The dissolving of CaCl2 in water is product-favored, but the temperature of the water gets colder...
The conversion of solid CO2 ("dry ice") to CO2 gas is product-favored at room temperature. What would be the signs for ΔG, ΔH, and ΔS at room temperature? CO2(s) --> CO2(g) ΔG = (+) ΔH = (+) ΔS = (-) ΔG = (-) ΔH = (+) ΔS = (-) ΔG = (+) ΔH = (+) ΔS = (+) ΔG = (-) ΔH = (+) ΔS = (+) ΔG = (-) ΔH = (-) ΔS = (+)
Dissolving 5.57 g of CaCl2 in enough water to make 288 mL of solution causes the temperature of the solution to increase by 3.77 oC. Assume the specific heat of the solution and density of the solution are the same as water′s (about 4.18 J/goC and 1.00 g/cm3, respectively) Calculate ΔH per mole of CaCl2 (in kJ) for the reaction under the above conditions. Hint given in feedback Aside, the ΔH per mole for dilution depends on the process. For...
When 23.6 g of calcium chloride, CaCl2, was dissolved in water in a constant-pressure calorimeter, the temperature rose from 25.0 C to 38.7 C. If the heat capacity of the solution and the calorimeter is 1258 J/C, what is the enthalpy change when 0.710 mol of calcium chloride dissolves in water? The solution process is CaCl2(s) --> Ca2+(aq) + 2Cl–(aq)
1. Consider a process at 286 K with ΔH = -72.5 kJ/mol and ΔS = -96.8 J/K mol Which of the following is true? ΔG = -44.8 kJ/mol and the process will not be spontaneous ΔG = +39.4 kJ/mol and the process will be spontaneous ΔG = -44.8 kJ/mol and the process will be spontaneous ΔG = -19.1 kJ/mol and the process will not be spontaneous ΔG = +39.4 kJ/mol and the process will not be spontaneous 2. Consider a...
1. The heat capacity of a calorimeter is given as 1264 J/oC. Suppose the enthalpy of solution for calcium chloride (MM=111 g/mol) in water is given by the thermochemical equation: CaCl2(s) + H2O(l) → Ca2+(aq) + 2Cl-(aq) ΔH = -81.0 kJ/mol. Calculate the temperature change if 11.1 g of calcium chloride is dissolved in water in the calorimeter. 2. Given the following data, calculate ΔH for the reaction of two moles of carbon monoxide with oxygen gasto give carbon dioxide....
Consider the reaction Ca(OH)2(aq) + 2HCl(aq)CaCl2(s) + 2H2O(l) for which H° = -30.20 kJ and S° = 205.9 J/K at 298.15 K. (1) Calculate the entropy change of the UNIVERSE when 1.934 moles of Ca(OH)2(aq) react under standard conditions at 298.15 K. Suniverse = ----------J/K (2) Is this reaction reactant or product favored under standard conditions? (3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is...
4. In an experiment, when 23.6 of calcium chloride, CaCl2 were dissolved in water in a coffee- cup calorimeter (at constant pressure), the temperature rose from 25.0°C to 38.7°C. The dissolution process is: CaCiz(s) - Ca2+ (aq) + 2C1-(aq) The heat capacity of the solution and the calorimeter is 1258 J/°C. The molar mass of CaCl2 is 110.98 g/mol. 1) Determine the heat that was absorbed by the solution and calorimeter. (1 point) 2) Determine the heat that was released...
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Thermodynamics of Potassium nitrate dissolving in water
KNO3(s) ↔
K+ (aq) +
NO3-(aq
Determine the thermodynamic variables, ΔG, ΔH, and ΔS, for the
dissolving of KNO3 in water. You will find these
variables by creating a Van’T Plot, which is a graph of
lnK(sp) vs 1/T.
A set amount of KNO3 is weighed and dissolved in 25mL
of water and heated until all the KNO3 is
dissolved....
A reaction has an equilibrium constant of Kp=0.061 at 27 ∘C. Part A Find ΔG∘rxn for the reaction at this temperature. Find for the reaction at this temperature. 6.98 kJ 0.839 kJ -6.98 kJ 0.628 kJ Part B Above what temperature does the following reaction become nonspontaneous? 2 H2S(g) + 3 O2(g) → 2 SO2(g) + 2 H2O(g) ΔH = -1036 kJ; ΔS = -153.2 J/K 298 K 158.7 K 6.762 × 103 K This reaction is nonspontaneous at all...
5. Potassium chloride (KCI) dissolves in water and establishes the following equilibrium in a satura solution: KCI (s)--K+ (aq) + (aq) The following table supplies information on the solubility of KCI as a function of the Celsius temperature. temp. C) Kp 20.0 40.0 60.0 80.0 13.3 66258 18.533 a 30.5 366 34 (a) Complete the entries in this table by converting the temperature to kelvins and calculating 1/T InKsp, and AG. (b) Plot InKxp as a function of 1/T. Determine...