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© THE TRANSITION METALS Naming complex cations with one type of ligand Name the following complex...
O THE TRANSITION METALS Determining the oxidation state of the metal in a coordination... Determine the oxidation state of the transition metal in each of these coordination compounds. compound oxidation state of the transition metal K,[Coc (1,0), D [TiBr(co),]CI [MocI,(NH) ]c, O THE TRANSITION METALS Naming complex cations with one type of ligand Write the chemical formula of the following complex ions. formula name tetraaquachromium(III) pentacarbonylcobalt(III) hexaaquairon(III)
O THE TRANSITION METALS Determining the oxidation state of the metal in a coordination... Determine the oxidation state of the transition metal in each of these coordination compounds. compound oxidation state of the transition metal Na [AuCl (co),] [PICI, (1,0)]BE [CB (NH4) ]c, 0 Name the following complex ions. formula name 0 [Au(NH,), [V(1,0))** [Mncı,]**
O THE TRANSITION METALS Naming coordination compounds Write the chemical formula of these coordination compounds. formula name sodium triamminetrichloronickelate(II) x 6 ? dibromotetracarbonylplatinum(IV) chloride potassium triaquatrichlorocuprate(11)
oct Original Color (M2+ H20) Complex Color (M2+/ Ligand) de calidad superior de haute qualité CI- Complex ion Formula Effect of H20 Cu2+ Complex ions: [Cucl.]2- changed BLUE ZEHIO NH3 dark en BLUE SCN- green Ni2+ Complex ions: CI- NH3 GREEN Ligand Effect of OH- green BLUE no change. bue I (NH) no change. Changed to (percip). cloudy/lignt bowe dariple ese (Haiche, no change. no change BLUE line neon [Cursen) i no change. Shangcaute changed to peras) Ligand cloudy out...
3. For the complex [Co(NHs) enl21SOs identify: (a) The denticity of the ligand (en) (b) the coordination number of the cobalt (c)themolecular arrangement of the complexion tariedal (d) the oxidation state of cobalt (e) the number of unpaired electrons in the complex assuming it is a low spin complex (0 the number of ions per formula unit based on conductance studies in aqueous solutio (g) if silver ion, Ag was added to an aqueous solution of the above complex, what...
2.(1) What does it mean when we say a transition metal complex (or a molecule) is chiral? 3.(3) Give the name or formula, as appropriate, for: a) [Co(CO)s]CO3 b) Ks[Fe(CN) 6] c) diaquabis(ethylenediamine)chromium(II) nitrate 4.(3) Give the coordination number, geometry, and hybridization of cobalt in [Co(NO2)2(en)2]2 5.(5) Draw all possible isomers of [CrNH)h(en)FJ. Label them as either geometrical or optical.
1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion: Name Coordination # (a) K[Fe(CN).] (b)Ks[Fe(ox).] (c) Cr(en).]C13 (d) (Cr(NH3):(HO)](NO3) (e)ky [Cr(NH3),Cla]
Q1. The following species a)-c) all contain complex ions of transition metals, which you can assume take up an octahedral geometry. a) [RuCl3(H2O)3] b) [Ir(bpy)3]Cl3 ; bipy = 2,2'-bipyridine c) K2[Mo(NCS)6] For each species: i) draw all the possible isomers of the complex ions; ii) calculate the charge of the metal, and the dn configuration; iii) draw a diagram showing d orbital occupancy and, where high and low spin cases are possible, predict which will be favoured considering the spectrochemical...
What is the coordination number for each of the following
complexes or compounds?
[Co(NH3)4Cl2]+
[Ca(EDTA)]2−
[Pt(NH3)4]2+
Na[Ag(CN)2]
Enter the coordination numbers, in the order that the complexes
are listed, as four integers separated by commas (e.g.,
1,2,3,4).
What is the charge on each of the following complex ions?
hexaaquairon(II), [Fe(H2O)6]?
tris(carbonato)aluminate(III), [Al(CO3)3]?
amminepentachloroplatinate(IV), [Pt(NH3)Cl5]?
Express the charges numerically, in the order that the complexes
are listed, separated by commas. For a nonzero charge, be sure to
include the sign (e.g.,...
1. The electron configuration of a Ti atom is A) [Ne]3s23d2 B) [Ne) 3s4d2 C) [Ar)4s23d E) IAr13d 2. The electron configuration of an Fe ion is 3?The total number of electrons in the 3d orbitals of a copper atom is A) 6 B) 7 C)8 D) 9 E) 10 4. How would you expect the molecule 1,10-phenanthroline (shown below) to function as a ligand? ?-? ?-? C--H A) B) C) It would be expected to be a monodentate ligand....