Ksp of AgCl = 1.77×10–10
AgCl ---------------> Ag+ + Cl-
Ksp = [Ag+][Cl-]
1.77×10–10 = S^2
S = 1.33 x 10^-5 M
solubility in water = 1.33 x 10^-5 M
when NaCl added :
AgCl ---------------> Ag+ + Cl-
S 0.1
Ksp = [Ag+][Cl-]
1.77×10–10 = S x 0.1
S = 1.77 x 10^-9 M
solubility when NaCl added = 1.77 x 10^-9 M
so the solubility of AgCl less than that of water
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