Question
use a diagram to explain why Ha appears more downfield than Hb or Hc in the 1H NMR.
H: 87.94 ppm Hb: 87.40 ppm H.: 87.40 ppm Acetophenone
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Answer #1

Ha is more downfield because of electron withdwawing nature of -CHO by Resonance as well as inductive effect which is maximum at ortho position i.e.Ha compared to meta and pera possition. Higher the elecctron deficiency more downfield the peak comes.

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