7. The number of π (pi) electrons in anthracene is: a. 6; b. 8; c. 10; d. 12; e. 14
8.Thiophene is a ---------------------------compound.
A)Five membered carbocyclic
B)Six membered heterocyclic
C)Seven membered cyclic
D)Five membered heteroaromatic
E)Aliphatic
10.A four membered, cyclic, planar, completely conjugated compound with sp2 hybridized carbons and 4p (pi) electrons will be: a. Heteroaromatic b. Aromatic c.Nonaromatic d. Antiaromatic e. None of the above
21.The stability of the carbocations is as follow:
A)1° carbocation > 2° carbocation > 3° carbocation
B)2° carbocation > 3° carbocation > 1° carbocation
C)2° carbocation > 1° carbocation > 3° carbocation
D)3° carbocation > 2° carbocation > 1° carbocation
E)None of the above
22.In the reaction “sulfonation of benzene” the name of the product is
A)Benzene sulfanilic acid
B)Benzene sulfonamide
C)Sulfanilic acid
D)Benzenesulfonic acid
E)Nitrobenzene
6. Phenanthrene is ----------------, ---------------- compound.
A)Bicyclic, aromatic
B)Substituted, antiaromatic
C)Tricyclic, aromatic
D)Alcoholic, nonaromatic
E)Acidic, antiaromatic
7. The number of π (pi) electrons in anthracene is: a. 6; b. 8; c. 10;...
For each structure below, determine the number of pi electrons
and indicate whether it is aromatic, nonaromatic, or
antiaromatic.
b) c) d)
2. Which of the following pi electrons in a cyclic compound meet the criteria of Hückel's rule? a. 4N b. 6N C. 4N42 d. 6N+2 3. From the following compounds having 10 pi electrons that meet Huckel's rule, circle on the aromatic ring. ??
13. In the molecular orbital model of benzene, how many pi electrons are delocalized about the ring? A) 2 в) з C) 4 D) 5 E) 6 14, In the molecularorinl model of benzene,ow manypi electrons are in bonding molecular orbitals? A) 6 B) 5 C) 4 D) 3 E) 2 15. Cyelopentadiene is unusually acidic for a hydrocarbon. An explanation for this is the following statement A) The carbon atoms of cyclopentadiene are all sp'-hybridized B) Cyclopentadiene is aromatic....
C) E1 D) E2 E) E1cb 24. Rank is first, slowest is last) the following compounds in order of increasing reacdtivity in an a veaion Br Br IV 2. In the molecular orbital representation of benzene, how many T molecular orbitals are present? A) 1 B) 2 C) 4 D) 6 E) 8 26. What is the major difference between an antiaromatic and aromatic compound? A) The structure must be cyclic for aromatic but not antiaromatic compounds. B) Antiaromatic compounds...
Please show work and explain!
If this problem is graded:50 Problem #10. Furan and thiophene are aromatic heterocycles that are similar in structure to the cyclopentadienyl anion. се a) Which of the following statements are TRUE for all three compounds? I. They are aromatic. II. All of the atoms in the ring are sp hybridized. 111. They are 4π electron systems. IV. They are weak bases. A) I, II, and III B) II and III C) III and IV D)...
a. Alkenes with electron withdrawing groups are good dienophiles-True/False b. Wolfkishner reaction is helpful to convert an ester to alkane. True false c. Tertiary alcohol will be formed by the reaction between a ketone and Grignard reagent True/ false d. A cyclic conjugated compound with 6 pi electron is aromatic- True/ False e. Addition of CO; to Methyl magnesium bromide is a nucleophilic addition Truel false f A good protecting group should be cleaved during the progress of the reaction-True...
Can you please answer all of them?
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect...
Please answer Questions 8,9,
& 10 and explain why please. Thanks!
8. Which compound is the reactant for this reaction? OH ? 1. NaOH (excess), 70°C 2. H30* NO2 H NO2 NO2 B. NO2 NO2 D Br NO2 E. A. C. 9. Which statement best describes the aromaticity and UV-vis spectra of these two substances? II A. Both are aromatic. The longest wavelength of absorbance of I is larger than that of II. B. Both are aromatic. The longest wavelength...
8. All of the C-C bonds of benzene are: a. the same length b. radical like in nature c. easy to break homolytically b. polyalkylation d. None of the above c. casy to break hetcrolytically 9. A limitation of the Friedel-Crafts acylation is: a. carbocation rearrangement c. reaction fails with very strong deactivators 10. Generally, the reaction with benzene with a halogen needsa as a promoter. a. Lewis base to serve b. Lewis acid c. Bronsted base d. Bronsted acid...
6). (10 points) Predict the mononitration products of the following compounds. a) o-nitrotoluene b) m-chlorotoluene c) o-bromobenzoic acid d) p-methoxybenzoic acid e) m-cresol (m-methylphenol) (Two products) (Three products) (Two products) (One product) (Three products) 7). (12 points) Show how you would synthesize the following aromatic derivatives from benzene. You don't have to show mechanisms just show synthesis pathways. a) p-tert-butylnitrobenzene b) p-toluenesulfonic acid c) p-chlorotoluene glad noeg banorte