1) NaNH2
2) CH3CH2CH2Cl
3) BH3/THF
4) H2O2, NaOH
Explanation: NaNH2 is a strong base which abstracts most acidic acetylene proton and produces acetylide anion which on alkylation with alkyl halide produces an extended carbon chain. Now, hydroboration - oxidation of alkyne with BH3, THF and H2O2, NaOH produces aldehyde as product.
Brz equiv 1 equiv NaN CH,CHact Lindar catalyst Huo Haso Hosor Bez 2 equiv
In each reaction box, place the best reagent and conditions from the list below. OOY NaBHA CH3CH2Br 2 equiv. NaNH2 Brz BHY/THF H2O2. NaOH, H20 SOCI HBR H2. Lindlar catalyst H20, H2SO4, HgSO4 bromocyclohexane excess NaNH2, then H2O CH3Br
What is the major product? Click on a molecule to answer. 1. Bez, hov 2. NaOEI, EIOH 3. BH3 4. H2O2, NaOH 5. Brz, FeBrz OH ca OH OH OH
Br Br excess NaNH, HBr, 2-equiv. Bry, 2-equiv. CH3Br NaBH4 PBr3 Hz. Lindlar cat. BH/THF NaOH. HBr, 1-equiv. Brz, 1-equiv. H30*
Draw the major organic products of this olefin metathesis reaction. Ignore stereochemistry. Ru catalyst 2 equiv.
Draw the major organic products of this olefin metathesis reaction. Ignore stereochemistry. Ru catalyst 2 equiv.
CH,CHE 1.CH,CH,NH, H 2. LIAME 3.HO CHCHCHCI 1. NaN, 2. Hz. Ni CHCH.CHCI 1. NOCN 2.Hy, Ni 1. HNO3, H2SO. 2. Hz, Ni NH2 excess CHI NaHCO3 I NEND, ICE 2 CON La CH3 1. NaNO,, Hal 2. CCN
syntheses 7-12. Syntheses: provide the product(s): он РСС , но* CH,Cl2 Brz 1. Brz/PBrg OH 2. H20 NaOH/HO 1. NaOCH2CH3 2. H307 1. (CH3CH2CH2)2Culi 2. Hz0
2. CuCN -CH₃ 1. N(CH3)2 2. Ag2O, H20 3.A Br 1. LiAlH4 Ph NaN 2. H20
Check work HBe (2 eq) 1-CH,CH Br H-Cac- Na 2.NaNH, 3 (CH,), CBr Lindlar's catalyst Lindlar catalyst CH H20 H2, Pd C KMnO4 CH CH a
Fill in the blank boxes. H-Br 1 equiv Kinetic conditions OMe + heat Meo H* catalyst HN 2x Na(CN)BH3 CH3-NH2 Меон then OH