A liquid-phase mixture of 450 mL of acetic acid, 300 mL of ethanol, 2.00 mL of water, and 2.00 mL ethyl acetate are mixed together at 298 K, where the following reaction will occur: CH3COOCH2CH3 +H2O CH3COOH +CH3CH2OH, Kc = 3440 Will the reaction occur from left-to-right or right-to-left (as written)? Please support your answer. (Hints: Can you calculate concentrations of the chemical species initially in appropriate units. Starting with the densities, i.e., specific gravities, and volumes, molar amounts of each species can be determine. Also, the total volume can be calculated; assume the volume change due to mixing the four solvents is zero. Can you calculate Qc?)
Substance Specific Gravity
Acetic Acid 1.049
Ethanol 0.785
Water 0.998
Ethyl Acetate 0.901
A liquid-phase mixture of 450 mL of acetic acid, 300 mL of ethanol, 2.00 mL of...
1.0 mol of ethanol and 1.0 mol of acetic acid are dissolved in water and kept at 100? degrees C. The volume of the solution is 250 mL. At equilibrium, 0.25 mol of acetic acid has been consumed in producing ethyl acetate. Calculate Kc? at 100 degrees C for the reaction: C2H5OH?(aq) + CH3CO2H(aq) CH3CO2C2H5(aq) + H2O?(l)
You are asked to prepare 500. mL of a 0.100 M acetate buffer at pH 5.00 using only pure acetic acid (MW=60.05 g/mol, pKa=4.76), 3.00 M NaOH, and water. Answer the following questions regarding the preparation of the buffer. 1. How many grams of acetic acid will you need to prepare the 500 mL buffer? Note that the given concentration of acetate refers to the concentration of all acetate species in solution. 2. What volume of 3.00 M NaOH must...
One type of breathalyzer employs a fuel cell to measure the quantity of alcohol in the breath. When a suspect blows into the breathalyzer, ethyl alcohol is oxidized to acetic acid at the anode: CH3CH2OH(g)+4OH−(aq)→HC2H3O2(g)+3H2O(l)+4e− At the cathode, oxygen is reduced: O2(g)+2H2O(l)+4e−→4OH−(aq) The overall reaction is the oxidation of ethyl alcohol to acetic acid and water. When a suspected drunk driver blows 185 mL of his breath through this breathalyzer, the breathalyzer produces an average of 325 mA of current...
The purpose of the lab was to find the equilibrium constant of the rxn of acetic acid and ethanol to yield ethyl acetate and water. Hydrochloric acid is used as a catalyst. We have to determine the equilibrium concentrations of all the species (water included) present at equilibrium. In test tubes, different concentrations of the equilibrium system were prepared then titrated with NaOH to determine the total acid content of the system at equilibrium. From this you will be able...
4, The 750 mL bottle of Lindeman's Shiraz wine in my kitchen is 7.75 % ethanol by volume. The density of ethanol is 0.789 g/mL. What is the molarity of the wine with respect to the solute ethanol? 5. To make a saturated aqueous solution of ammonia, 470 g of ammonia are dissolved with one liter of water. The density of the resulting solution is 0.89 g/mL. What is the molarity of the solution? Hint: Think about the two quantities...
17. Determine the enthalpy change for the oxidation of ethanol to acetic acid, CH3CH2OH(() + O2(g) → CH3COOH() + H2O(1) given the thermochemical equations below. 1) 2 CH2CH2OH(1) + O2(g) + 2 CH CHO(l) + 2 H20(1) AH = -400.8 kJ/mol-rxn 2) 2 CHỊCHO(0)+0g)+2 CHCOOH(C). A,Hº = -584.4 kJ/mol-rxn (a) What is the compound that is not present in the target equation? (b) To cross out that compound, what operation is needed to do for equations 1) and 2)? (c)...
In the titration below acetic acid (CH CooH)i (a) What is the volume of NaOH used to neutralize the acetic ac neutralized with 0.5 M NaOH. id? (3 pts) (b) What is the concentration of the acetic acid solution? (7 pts) nial Reading 15m Burette Final Reading 32 ml NeDH (aq Known Concentraton )+20mt_灬| 1 of Total volume of 2 on vnegar ies 5 drops acetic acid 25ml c) An acid solution is titrated to the end point by a...
please answer the full thing 1. What would be the AE (in kJ) for the following reaction if 6.300 moles of H20 were decomposed? 2 H2O + 2H2 + O AE = 483.6 kJ (for reaction as written) 2. The value of AE for the reaction below is -336 kJ. Determine the amount of heat (in kJ) evolved when 13.0 g of HCl is formed. CH4(9) + 3 Cl2(g) - CHCI) + 3HCIO) 3. If 1.00 cal = 4.18 J,...
Thank you very much in advance. Emrah Acetic acid and ethanol react to form ethyl acetate and water, like this: Imagine 53. mmol of HCH, CO, are added to a flask containing a mixture of HCH,CO, CH,OH, C,H,CO,CH, and H,0 at equlbnum, and then answer the following questions. O zero. What is the rate of the forward Greater than zero, but less than the rate of the reverse reaction. reaction before any HCH,002 has been added to the lask? O...
It's a weak acid strong base titration Experiment 4: Identification of an unknown acid by titration Page 2 of 15 Background In this experiment, you will use both qualitative and quantitative properties to determine an unknown acid's identity and concentration. To do this analysis, you will perform a titration of your unknown acid sample-specifically a potentiometric titration where you use a pH meter and record pH values during the titration, combined with a visual titration using a color indi- cator...