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Question 2. (20 marks) In the reactions below, draw the MAJOR product in the box provided and indicate in the small box...
In the substitution reactions below, draw the major product in the box provided and indicate in...
In the substitution reactions below, draw the major product in the box provided and indicate in the small box whether the reaction is SN1, SN2, or neither. Be sure to show all stereochemistry. If more than one enantiomer is produced, write "+Enant" in the box with the product. [10] Product SN1/SN2/Neither NaCN Br DMSO NaOEt EtOH Br NaOMe MeOH NaOH Expensive Acetonitrile CH,Br DMF Nat
3. For each reaction, draw the structure of the major product(s) including stereochemistry where appropriate. Fill n t...
3. For each reaction, draw the structure of the major product(s) including stereochemistry where appropriate. Fill n the box below each arrow with the mechanism(s) that will be followed (SN1/E1, SN2, or E2). For SN1/E1 reactions, draw products for both. NaCN DMF tBuOH 言言言 MeOH * | CH30 CH OH DMSO R-2-bromopentane
Draw the major product and label as SN2, SN1, E2, or E1 7. Draw the major...
Draw the major product and
label as SN2, SN1, E2, or E1
7. Draw the major products of the following reactions, and label the reaction as SN2, SN1, E2 E1. (Darkly shaded bonds are wedged) Br NaOMe NaCN H2SO4 OTs NaSH OTs H20 NaOMe Br KOtBu OH HBr HBr OH
4. Predict the products of the following reactions & indicate whether they are most likely to...
4. Predict the products of the following reactions & indicate whether they are most likely to go through an SN2, SN1, E1, or E2 mechanism. NaCN DMSO NaOH CH3OH heat Only one product is formed in the following E2 elimination reaction. Draw an arrow-pushing mechanism for the reaction and provide the correct product structure. Include a 3-D drawing (chair conformation) displaying proper stereochemistry of the transition state to explain formation of only the major product. CH3 •Br NaOCH3 ~"'CHS
1. For the following reactions, show the major organic product(s) in the box provideed. Make sure...
1. For the following reactions, show the major organic product(s) in the box provideed. Make sure to show appropriate stereochemistry wherever necessary. Underneath the box, mention the mechanism (SN1, El, S2, or E2) that leads to the major products and also show the arrow pushing mechanism. Understand that the compound listed below the arrow is solvent. (a) Br O Na DMSO Mechanism: (b) NaOH Н-о Mechanism: Organic Chemistry C341 (e) CHCH Oн 4 Mechanism: (d) NaOMe E1OH Mechanism: (e) BeOK...
3. Predict the major product (only one product) in each of the following reactions and indicate...
3. Predict the major product (only one product) in each of the
following reactions and indicate the type of mechanism.
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism Sn2 Sn1 HO HBr moy ng heo 0°C, H2O E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr SN2 Sn1 rt, H20 E2 E1 OH
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
(3 pt) For the following reactions: a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,...
(3 pt) For the following reactions:
a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,
Strong/Weak Base) and solvent (protic, aprotic).
b) Determine what mechanism will predominate (SN1, SN2, E1, or
E2).
c) Draw the product(s) you would expect to form, paying
attention to regioselectivity and stereoselectivity.
4. (3 pt) For the following reactions: a) Label the substrate (1º, 2º, 3º), reagent (Good/Poor Nu, Strong/Weak Base) and solvent (protic, aprotic). b) Determine what mechanism will predominate (SN1, SN2, E1,...
4. Draw the organic product of these reactions. Note that in so some cases, a 2-step...
4. Draw the organic product of these reactions. Note that in so some cases, a 2-step process is written in this form. 1. reagents for 1st step REACTANT - PRODUCT 2. reagents for 2nd step OH + HB m i + HCI- + HCI + conc. H2SO4(aq) heat OH 1. NaOH 2. 1. mCPBA 2. H30+ 1. NaH CrO3, H2SO4(aq) OH acetone 5. State the major pathway by which these reactions wo product of that pathway. way by which these...
3. Predict the major product (only one product) in each of the following reactions and indicate...
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism SN2 Sn1 HO HBr 0°C, H20 E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr Sn2 Sn1 rt, H20 E2 E1
In the substitution reactions below, draw the major product in the box provided and indicate in the small box whether the reaction is SN1, SN2, or neither. Be sure to show all stereochemistry. If more than one enantiomer is produced, write "+Enant" in the box with the product. [10] Product SN1/SN2/Neither NaCN Br DMSO NaOEt EtOH Br NaOMe MeOH NaOH Expensive Acetonitrile CH,Br DMF Nat
3. For each reaction, draw the structure of the major product(s) including stereochemistry where appropriate. Fill n the box below each arrow with the mechanism(s) that will be followed (SN1/E1, SN2, or E2). For SN1/E1 reactions, draw products for both. NaCN DMF tBuOH 言言言 MeOH * | CH30 CH OH DMSO R-2-bromopentane
Draw the major product and
label as SN2, SN1, E2, or E1
7. Draw the major products of the following reactions, and label the reaction as SN2, SN1, E2 E1. (Darkly shaded bonds are wedged) Br NaOMe NaCN H2SO4 OTs NaSH OTs H20 NaOMe Br KOtBu OH HBr HBr OH
4. Predict the products of the following reactions & indicate whether they are most likely to go through an SN2, SN1, E1, or E2 mechanism. NaCN DMSO NaOH CH3OH heat Only one product is formed in the following E2 elimination reaction. Draw an arrow-pushing mechanism for the reaction and provide the correct product structure. Include a 3-D drawing (chair conformation) displaying proper stereochemistry of the transition state to explain formation of only the major product. CH3 •Br NaOCH3 ~"'CHS
1. For the following reactions, show the major organic product(s) in the box provideed. Make sure to show appropriate stereochemistry wherever necessary. Underneath the box, mention the mechanism (SN1, El, S2, or E2) that leads to the major products and also show the arrow pushing mechanism. Understand that the compound listed below the arrow is solvent. (a) Br O Na DMSO Mechanism: (b) NaOH Н-о Mechanism: Organic Chemistry C341 (e) CHCH Oн 4 Mechanism: (d) NaOMe E1OH Mechanism: (e) BeOK...
3. Predict the major product (only one product) in each of the
following reactions and indicate the type of mechanism.
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism Sn2 Sn1 HO HBr moy ng heo 0°C, H2O E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr SN2 Sn1 rt, H20 E2 E1 OH
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
(3 pt) For the following reactions:
a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,
Strong/Weak Base) and solvent (protic, aprotic).
b) Determine what mechanism will predominate (SN1, SN2, E1, or
E2).
c) Draw the product(s) you would expect to form, paying
attention to regioselectivity and stereoselectivity.
4. (3 pt) For the following reactions: a) Label the substrate (1º, 2º, 3º), reagent (Good/Poor Nu, Strong/Weak Base) and solvent (protic, aprotic). b) Determine what mechanism will predominate (SN1, SN2, E1,...
4. Draw the organic product of these reactions. Note that in so some cases, a 2-step process is written in this form. 1. reagents for 1st step REACTANT - PRODUCT 2. reagents for 2nd step OH + HB m i + HCI- + HCI + conc. H2SO4(aq) heat OH 1. NaOH 2. 1. mCPBA 2. H30+ 1. NaH CrO3, H2SO4(aq) OH acetone 5. State the major pathway by which these reactions wo product of that pathway. way by which these...
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism SN2 Sn1 HO HBr 0°C, H20 E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr Sn2 Sn1 rt, H20 E2 E1
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