Question

1)

For the following reaction. 25.6 grams of sulfur dioxide are allowed to react with 6.09 grams of water. sulfur dioxide (g) +

2)

For the following reaction. 39.5 grams of sulfuric acid are allowed to react with 26.9 grams of calcium hydroxide. sulfuric a

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Answer #1

1. Sol :-

Given, mass of SO2 = 25.6 g

Gram molar mass of SO2 = 64 g/mol

Number of moles of SO2 gas = Given mass of SO2 / Gram molar mass of SO2

= 25.6 g / 64 g/mol

= 0.40 mol

Similarly,

mass of H2O = 6.09 g

Gram molar mass of H2O = 18 g/mol

Number of moles of H2O = Given mass of H2O / Gram molar mass of H2O

= 6.09 g / 18 g/mol

= 0.338 mol

ICF table of the given reaction is :

..............................SO2 (g).............+............H2O (l) <--------------------> H2SO3 (g)

Initial (I)..................0.40 mol..........................0.338 mol..........................0.0 M

Change (C)............-0.338 mol.......................-0.338 mol..........................+0.338 mol

Final (F)...................0.062 mol.........................0.0 mol.................................0.338 mol

Limiting reagent formula = H2O

Excessive reagent = SO2 (g) Limiting reagent :- Which is completely consumed in a chemical reaction.

Excessive reagent = Whose amount remains left after the completion of chemical reaction

Mass of excessive reagent left = Moles x Gram molar mass

= 0.062 mol x 64 g/mol

= 3.968 g

Hence, Mass of excessive reagent remains in the solution = 3.968 g

Mass of products formed = Moles x Gram molar mass

= 0.338 mol x 82.07 g/mol

= 27.740 g

Hence, Maximum amount of H2SO3 formed = 27.740 g  
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