Question

1. The species that contributes the pertinent HOMO in the FMO interaction is relatively electron (rich/poor), it is the Lewis (acid/base). 2. The species that contributes the pertinent LUMO in the FMO interaction is relatively electron (rich/poor), it is the Lewis (acid/base). 3. What is an appropriate name for the following compound? 4. Ketones take priority over alcohols. What is an appropriate name for the following compound? OOH

Answer 1

Rich, Base HOMO means Highest Occupied Molecular 0nbital. Jt is the highest enengy Mo that has Iy it 3t behaves as a base because the elecbons elecbrons grom the HDMD Cre lonated to Luno CA ccording to Lewis concept, anY electron paur donor 1& a base) Poorr, Acid LUMD means Lowest Unoccupied Motecular 0rubital 91 accepts electons pom the Homo The LUMO is Lowest energy place to put or excite arn electron Since LUMO accepts electrme, it behaveg as an acid ( Accopiding to Levois concatt, arr electeun pair acceptor is the &Lewis acid 4 7 (1s,3z)-3-ycloocten-1-6 3 12 но Explanatiosn The dluble bond present (T the in cis positien Sing sytem is

И z-conkiguration cis-a CH2 &teneodesvitony fer the chirf centre is S The priority ordlesy llows: The -0H> -C-C=cーフ -C-c-c> H 3 01 2 ketones take Ppriority over alcohds The name o the giver combbund is 4-Hysdboxy-4-methyfpentan-2-one Explaratien The longest chun Caubon is ef cbon atons, thorepore the word uot is pent(a) Hyclory goup is writtern ou prefix while ketone iA writerr as rieipal bunctimal up