Determine values for the constants n and k (Equation 10.17) for the crystallization of polypropylene (Figure 15.17) at 150°C.
Figure 15.17 Plot of normalized fraction crystallized versus the logarithm of time for polypropylene at constant temperatures of 140°C, 150°C, and 160°C.
(Adapted from P. Parrini and G. Corrieri, “The Influence of Molecular Weight Distribution on the Primary Recrystallization Kinetics of Isotactic Polypropylene,” Die Makromolekulare Chemie, 1963, Vol. 62, p. Copyright Wiley-VCH Verlag GmbH&Co. KGaA. Reproduced with permission.)
(10.17)
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