For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to
where σ(t) and σ(0) represent the time-dependent and initial (i.e., time = 0) stresses, respectively, and t and τ denote elapsed time and the relaxation time, respectively; τ is a time-independent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation 7.33 was suddenly pulled in tension to a measured strain of 0.6; the stress necessary to maintain this constant strain was measured as a function of time. Determine Er(10) for this material if the initial stress level was 2.76 MPa (400 psi), which dropped to 1.72 MPa (250 psi) after 60 s.
(7.33)
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