Problem

The vapor-phase cracking of gas-oil in Example 10-8 is canied out över a dif-ferent cataly...

The vapor-phase cracking of gas-oil in Example 10-8 is canied out över a dif-ferent catalyst, for vvhich the rate law is

(a) Assuming that you can vary the entering pressure and gas velocity, what operating conditions vvould you recommend?


(b) What could go wrong vvith the conditions you chose?


Now assume the decay law is

where the concentration, Ccoke, in mol/dm3, can be determined from a stoichiometric table.

(c) For a temperature of 400°C and a reactor height of 15 m, vvhat gas velocity do you recommend? Explain. What is the corresponding conversion?


(d) The reaction is now to be carried in an STTR 15 m high and 1.5 m in diameter. The gas velocity is 2.5 m/s. You can operate in the temperature range between 100 and 500°C. What temperature do you choose, and what is the corresponding conversion?


(e) What vvould the temperature-time trajectory look like for a CSTR?


Additional information:

ER = 3000 cal/mol

ED = 15,000 cal/mol

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Solutions For Problems in Chapter 10