Problem

The dehydrogenation of methylcyclohexane (M) to produce toluene (T) was carried out over a...

The dehydrogenation of methylcyclohexane (M) to produce toluene (T) was carried out over a 0.3% Pt/A12O3 catalyst in a differential catalytic reactor. The reaction is carried out in the presence of hydrogen (H2) to avoid coking [J. Phys. Chem., 64, 1559 (1960)].

(a) Determine the model parameters for each of the following rate laws.

Use the data in Table P10-15 B.

(b) Which rate law best describes the data? (Hint: Neither  or KM can take on negative values.)

(c) Where would you place additional data points?

TABLE P10-15. Dehydrogenation of Methylcyclohexane

 (atm)

PM (atm)

Reaction Rate

1

1

1.2

1.5

1

1.25

0.5

1

1.30

0.5

0.5

1.1

1

0.25

0.92

0.5

0.1

0.64

3

3

1.27

1

4

1.28

3

2

1.25

4

1

1.30

0.5

0.25

0.94

2

0.05

0.41

 

 

 

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