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15. The standard Gibbs free energy change (AG%) for the Haber reaction at 298K is -2.83...
16. For the following reactions, predict whether they will tend to be spontaneous at either high...
16. For the following reactions, predict whether they will tend to be spontaneous at either high or low temperatures, or at all temperatures, or at no temperature (10.0 points) a) H2(g) + 12(g) → 2HI(g) AH = -220 kJ b) 3S2(g) → 253(g) AH = +227 kJ c) H2O(l) → H2O(g) AH = +44 kJ d) H2(g) + '/gS8(g) → H2S(1) AH = -247 kJ
Gibbs free energy change AG is defined as AG= AH-TAS. For a spontaneous process, AG<0. For...
Gibbs free energy change AG is defined as AG= AH-TAS. For a spontaneous process, AG<0. For a. reversible reaction at equilibrium, AG = 0. The equilibrium constant K of the reversible reaction is relate- AG"=-RTIn(K). Symbol 40" refers to thermodynamics standard condition: 298 K and 1 atm. Exercise:consider the following reaction: bo:pfoiex 2 HNO:(aq)+NO(g)- 3 NO2(g) + H2O(I) AH=+136.5 kJ; AS = +287.5 J/K a. Below what temperature does the following reaction becomes nonspontaneous? niliod sis anotsole s ob io...
21A. Calculate the standard free energy change, AGºat 298 K for the reaction 2COXg) + 2NO(g)...
21A. Calculate the standard free energy change, AGºat 298 K for the reaction 2COXg) + 2NO(g) -2CO(g) + N:(g) The standard free energy of formation for CO is - 137 kJ, for NO it is 87.6 kJ/mol and for CO, it is -394 kJ/mol. B. Calculate the free energy change. AG. at 298 K. given that the partial pressure of CO is 5.0 atm, that of NO is 4.0 atm, that of CO, is 3.0 atm & that of N,...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(1) ► CO2(g) + 2NH3(g) Substance CO(NH3)2(aq) H00 AH(kJ/mol) 1-391.2 -285.9 -3935 -46.19 S'J/mol K) 173.8...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(l) → CO2(g) + 2NH3(g) Substance CO(NH2)2(aq) H2O(1) CO2(g) NH AH° (kJ/mol) -391.2 -285.9 -393.5 -46.19...
Consider the reaction: 2HBr(g)—„H2(g) + Br26) Using standard thermodynamic data at 298K, calculate the free energy...
Consider the reaction: 2HBr(g)—„H2(g) + Br26) Using standard thermodynamic data at 298K, calculate the free energy change when 1.84 moles of HBr(g) react at standard conditions. AG°rxn= C kJ
Since the computed value for AG is positive, the reaction is nonspontaneous under these conditions. Check...
Since the computed value for AG is positive, the reaction is nonspontaneous under these conditions. Check Your Learning Calculate the free energy change for this same reaction at 875 °C in a 5.00 L mixture containing 0.100 mol of each gas. Is the reaction spontaneous under these conditions? ANSWER: AG = +45.1 kJ/mol; no EXAMPLE 16.12 Calculating AG under Nonstandard Conditions What is the free energy change for the process shown here under the specified conditions? T = 25 °C,...
please help with these Fe2O3(s) + 3H2(g) +2Fe(s) + 3H2O(g) Using standard absolute entropies at 298K,...
please help with these
Fe2O3(s) + 3H2(g) +2Fe(s) + 3H2O(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 2.37 moles of Fe2O3() react at standard conditions. AS system JK 2CO(g) + O2(g) +2CO2(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 1.54 moles of CO(g) react at standard conditions. AS system JK 2NH3(g) + 3N20(g)— 4N2(g) + 3H2O(g) AH = -879.5 kJ and AS° = 288.1 J/K The...
(CM13201_S20), Calculate the value of the free energy change, AG, for the reaction below at 127.0°C...
(CM13201_S20), Calculate the value of the free energy change, AG, for the reaction below at 127.0°C when the pressures of NOCI (g) = 5.00 atm, NO (g) = 0.0200 atm, and Cl (g) - 0.0100 atm. 2 NOCI (9) - 2 NO (g) + Cl2 (g) AG° = 41.00 kj AH° = 77.08 kJ AS° = 121.24 J/K AGE Check
DI Question 3 2 pts The AG (change in Gibbs free energy at standard biochemical state)...
DI Question 3 2 pts The AG (change in Gibbs free energy at standard biochemical state) for the reaction below is -8.6 kJ/mol. What is ao for this reaction at 37°C when [A)-0.2 M [B-0.2 M, (C]-0.4 M, and ID)-0.6 M? ABCDase A BCD 3.98 J/mol O -4.16 KJ/mol 0-13.22kJ/mol 0 6.81k/moll DI Question 4 2 pts Which one of the following statements is true? 0 if ΔG is negative, the reaction will be spontaneous. Exothermic reactions are always spontaneous....
16. For the following reactions, predict whether they will tend to be spontaneous at either high or low temperatures, or at all temperatures, or at no temperature (10.0 points) a) H2(g) + 12(g) → 2HI(g) AH = -220 kJ b) 3S2(g) → 253(g) AH = +227 kJ c) H2O(l) → H2O(g) AH = +44 kJ d) H2(g) + '/gS8(g) → H2S(1) AH = -247 kJ
Gibbs free energy change AG is defined as AG= AH-TAS. For a spontaneous process, AG<0. For a. reversible reaction at equilibrium, AG = 0. The equilibrium constant K of the reversible reaction is relate- AG"=-RTIn(K). Symbol 40" refers to thermodynamics standard condition: 298 K and 1 atm. Exercise:consider the following reaction: bo:pfoiex 2 HNO:(aq)+NO(g)- 3 NO2(g) + H2O(I) AH=+136.5 kJ; AS = +287.5 J/K a. Below what temperature does the following reaction becomes nonspontaneous? niliod sis anotsole s ob io...
21A. Calculate the standard free energy change, AGºat 298 K for the reaction 2COXg) + 2NO(g) -2CO(g) + N:(g) The standard free energy of formation for CO is - 137 kJ, for NO it is 87.6 kJ/mol and for CO, it is -394 kJ/mol. B. Calculate the free energy change. AG. at 298 K. given that the partial pressure of CO is 5.0 atm, that of NO is 4.0 atm, that of CO, is 3.0 atm & that of N,...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(1) ► CO2(g) + 2NH3(g) Substance CO(NH3)2(aq) H00 AH(kJ/mol) 1-391.2 -285.9 -3935 -46.19 S'J/mol K) 173.8...
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(l) → CO2(g) + 2NH3(g) Substance CO(NH2)2(aq) H2O(1) CO2(g) NH AH° (kJ/mol) -391.2 -285.9 -393.5 -46.19...
Consider the reaction: 2HBr(g)—„H2(g) + Br26) Using standard thermodynamic data at 298K, calculate the free energy change when 1.84 moles of HBr(g) react at standard conditions. AG°rxn= C kJ
Since the computed value for AG is positive, the reaction is nonspontaneous under these conditions. Check Your Learning Calculate the free energy change for this same reaction at 875 °C in a 5.00 L mixture containing 0.100 mol of each gas. Is the reaction spontaneous under these conditions? ANSWER: AG = +45.1 kJ/mol; no EXAMPLE 16.12 Calculating AG under Nonstandard Conditions What is the free energy change for the process shown here under the specified conditions? T = 25 °C,...
please help with these
Fe2O3(s) + 3H2(g) +2Fe(s) + 3H2O(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 2.37 moles of Fe2O3() react at standard conditions. AS system JK 2CO(g) + O2(g) +2CO2(g) Using standard absolute entropies at 298K, calculate the entropy change for the system when 1.54 moles of CO(g) react at standard conditions. AS system JK 2NH3(g) + 3N20(g)— 4N2(g) + 3H2O(g) AH = -879.5 kJ and AS° = 288.1 J/K The...
(CM13201_S20), Calculate the value of the free energy change, AG, for the reaction below at 127.0°C when the pressures of NOCI (g) = 5.00 atm, NO (g) = 0.0200 atm, and Cl (g) - 0.0100 atm. 2 NOCI (9) - 2 NO (g) + Cl2 (g) AG° = 41.00 kj AH° = 77.08 kJ AS° = 121.24 J/K AGE Check
DI Question 3 2 pts The AG (change in Gibbs free energy at standard biochemical state) for the reaction below is -8.6 kJ/mol. What is ao for this reaction at 37°C when [A)-0.2 M [B-0.2 M, (C]-0.4 M, and ID)-0.6 M? ABCDase A BCD 3.98 J/mol O -4.16 KJ/mol 0-13.22kJ/mol 0 6.81k/moll DI Question 4 2 pts Which one of the following statements is true? 0 if ΔG is negative, the reaction will be spontaneous. Exothermic reactions are always spontaneous....
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