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2 of 6 04-Chem-A4/Dec 2012 1. A first-order, homogeneous, liquid-phase reaction (A - B) occurs in a CSTR that operates adiabatically at steady state. The reaction is exothermic. Data are as follows and should be considered as exact quantities CA G, 1.75 molA/L (Inlet concentration of A) 2.5 J/g-K (The heat capacity of the reacting fluid; assumed constant at all conversions.) AH, -27 000 J/molA q-30 L/min (Flow into the CSTR.) (-rA) = 1.8( 1013)e(-84000 RDCA (The rate of reaction [molA/Ls], R = 8.314 [J/mol-K]; T is in [KD. To 315 K (Inlet temperature of the feed.) V = 28 L (Reactor volume) XA 0.9 (Conversion of A leaving the reactor.) p 500 gL (Liquid density, assumed constant throughout the reaction.) a) What are the units of the constant 1.8(1013) in the rate equation? (2 marks) b) Calculate the temperature at which this reactor operates under steady operating conditions. (10 marks) c) Calculate the rate constant for conditions within the CSTR. (4 marks) d) Calculate the rate of heat evolved within this reactor (in J/s) during steady-state operation. (4 marks)
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