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The pi electrons of an alkene can act as a base. Explain why the cis-dibenzoylethylene produced...

The pi electrons of an alkene can act as a base. Explain why the cis-dibenzoylethylene produced can be isomerized back into trans-dibenzoylethylene by heating an ethanol solution of cis-dibenzoylethylene with a few drops of H2SO4.

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Answer #1

When the pi bond is protonated, there is free rotation around the remaining single sigma bond allowing the more stable trans isomer to form when deprotonation occurs reforming the pi bond between the central carbon atoms.

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answered by: zahid
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