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1. Drawing of carbohydrate structures (2.5 pts) - a) Draw the ring structures of the trisaccharide...
Draw the structure of the polysaccharide alpha-D-Glucopyranosyl- 1-> 3- beta-D-mannopyranosyl – 1->6 - alpha-D-fructopyranose in the chair...
Draw the structure of the polysaccharide alpha-D-Glucopyranosyl- 1-> 3- beta-D-mannopyranosyl – 1->6 - alpha-D-fructopyranose in the chair and Haworth configuration, showing the appropriate glycosidic linkages. Does this polysaccharide have free anomeric hydroxyl groups? If so, circle them in the structure you have drawn.
Draw the following monosaccharides in the chain form (not ring form): Write the chemical formula for...
Draw the following monosaccharides in the chain form (not ring form): Write the chemical formula for both glucose and fructose: What molecular similarities, in structure, are there between the glucose and fructose molecules? What are the differences? What are these two molecules called in relation to one another? , Draw the formation of a-glucose and a P-glucose starting from the chain form using your book (page 73) as a guide, (use chemical symbols) alpha-glucose beta-glucose In equation format, draw formation...
The Haworth structure of sophorose, a carbohydrate found in beans, is shown below. (5 pts) a...
The Haworth structure of sophorose, a carbohydrate found in beans, is shown below. (5 pts) a Is this a mono-, di-, or polysaccharide? Sophorose Hb) What monosaccharide units are present in sophorose? OH H но он c) Draw an arrow to each anomeric carbon atom. d) What type of glycosidic linkage exists in this carbohydrate? e) Is this an α or β isomer? Choose one. OH H нон
PRE-LABORATORY ASSIGNMENT Carbohydrates 1. Draw the structures of fructose (ring structures) present in a solution at...
PRE-LABORATORY ASSIGNMENT Carbohydrates 1. Draw the structures of fructose (ring structures) present in a solution at equilibrium. 2. An unknown carbohydrate showed a positive test reaction when tested with Fehling's reagent, turned red when reacted with Seliwanoff's reagent, and reacted quickly with Barfoed's reagent. What conclusions can be made about this compound? 3. What test could be used to differentiate between the compounds in each set? a. sucrose and maltose b. fructose and glucose c. lactose and glucose
1- Sucrose does not react with Fehling's reagent because A- Sucrose is not a reducing sugar....
1- Sucrose does not react with Fehling's reagent because A- Sucrose is not a reducing sugar. B) The anomeric carbon of glucose is involved in the glucose- fructose bond and hence is not free to form the aldehyde in solution. C) The monosaacharide constituents of sucrose no longer have an anomeric carbon with a free potential aldehyde or ketone group, and therefore no longer exhibits reducing properties. D) sucrose is a disaccharide of glucose and fructose in which the oxygen...
18. Which of the following compound(s) would undergo mutarotation in aqueous solution? 19. Draw the chair...
18.
Which of the following compound(s) would undergo mutarotation in
aqueous solution?
19. Draw the chair conformation of a-D-galactopyranose.
20. Which of the following compound(s) is a glycoside?
21. Provide the reagents neccesary to carry out the following
conversion.
22. Predict the product(s) for the following reaction.
23. D-glucose & D-galactose are ______epimers of each
other.
24. Predict the product(s) for the following reaction.
25. Which of the following compound(s) would produce D-glucose
and D-mannose when treated with HCN followed...
41. The following sugar is also called frukt sugar A Glucose Maltese Lactose Section 11 Sucrose ) Fructose 42. The...
41. The following sugar is also called frukt sugar A Glucose Maltese Lactose Section 11 Sucrose ) Fructose 42. The following ugaris Afructose Sucrose caled blood sugar Lactose Glucose E) Matose 43. Alactone is a cyclic Calcohol Detone Section 111 44. Refer to the above ructures the enantiomer of Duco A) D-Fructo -Gluco C L-Glucose Dj L-Idee Section 111 D-Galactose 45. Refer to the above structures. The diastereoisomers of Glucose indude all of these, except AD Galactose Glucose -dose D-Fructose...
PART E: Drawing structures that have the same chemical formu of atoms (i.e. isomers). Question :Draw...
PART E: Drawing structures that have the same chemical formu of atoms (i.e. isomers). Question :Draw AT LEAST THREE DIFFERENTline structures that hructures ard of CsHio. (you may find Chapter 12 of the their normal bonding patterns! Grade 0.5pt per structure Structures that have the san E DIFFERENT line structures that have a molecular formula e ch McMurry lecture text helpful). Make sure all atoms are following Structure 1 Structure 2 Structure 3 Question 2: How many tetrahedral carbon atoms...
1. Which of the folowing statements about glucokinase and hexokinase (that catalyze the same reaction) is...
1. Which of the folowing statements about glucokinase and hexokinase (that catalyze the same reaction) is TRUE? A. Glucokinase has a higher capacity than hexokinase to convert glucose to glucose 6 phosphate B. Hexokinase is only active in the liver where it can utilize multiple hexoses C. While glucokinase requires ATP for its action, hexokinase requires GTP D. Glucokinase can act on multiple glucose-like sugars (such as galactose) E. Hexokinase has a higher Km and easily handles all the glucose...
EO 3- resonance structures, formal charges, stability 1. Draw ONE possible significant additional resonance structure for...
EO 3- resonance structures, formal charges, stability
1. Draw ONE possible significant additional resonance structure for each of the following ions. Use curved arrows to show the movement of electrons that creates each new resonance structure. (Hint: lone pairs are not shown. Start by drawing in all one pairs, and include all lone pairs and formal charges in your additional resonance structure.) Page 1 of 3 2. For each structure, draw the resonance structure that is indicated by the curved...
Draw the following monosaccharides in the chain form (not ring form): Write the chemical formula for both glucose and fructose: What molecular similarities, in structure, are there between the glucose and fructose molecules? What are the differences? What are these two molecules called in relation to one another? , Draw the formation of a-glucose and a P-glucose starting from the chain form using your book (page 73) as a guide, (use chemical symbols) alpha-glucose beta-glucose In equation format, draw formation...
The Haworth structure of sophorose, a carbohydrate found in beans, is shown below. (5 pts) a Is this a mono-, di-, or polysaccharide? Sophorose Hb) What monosaccharide units are present in sophorose? OH H но он c) Draw an arrow to each anomeric carbon atom. d) What type of glycosidic linkage exists in this carbohydrate? e) Is this an α or β isomer? Choose one. OH H нон
PRE-LABORATORY ASSIGNMENT Carbohydrates 1. Draw the structures of fructose (ring structures) present in a solution at equilibrium. 2. An unknown carbohydrate showed a positive test reaction when tested with Fehling's reagent, turned red when reacted with Seliwanoff's reagent, and reacted quickly with Barfoed's reagent. What conclusions can be made about this compound? 3. What test could be used to differentiate between the compounds in each set? a. sucrose and maltose b. fructose and glucose c. lactose and glucose
18.
Which of the following compound(s) would undergo mutarotation in
aqueous solution?
19. Draw the chair conformation of a-D-galactopyranose.
20. Which of the following compound(s) is a glycoside?
21. Provide the reagents neccesary to carry out the following
conversion.
22. Predict the product(s) for the following reaction.
23. D-glucose & D-galactose are ______epimers of each
other.
24. Predict the product(s) for the following reaction.
25. Which of the following compound(s) would produce D-glucose
and D-mannose when treated with HCN followed...
41. The following sugar is also called frukt sugar A Glucose Maltese Lactose Section 11 Sucrose ) Fructose 42. The following ugaris Afructose Sucrose caled blood sugar Lactose Glucose E) Matose 43. Alactone is a cyclic Calcohol Detone Section 111 44. Refer to the above ructures the enantiomer of Duco A) D-Fructo -Gluco C L-Glucose Dj L-Idee Section 111 D-Galactose 45. Refer to the above structures. The diastereoisomers of Glucose indude all of these, except AD Galactose Glucose -dose D-Fructose...
PART E: Drawing structures that have the same chemical formu of atoms (i.e. isomers). Question :Draw AT LEAST THREE DIFFERENTline structures that hructures ard of CsHio. (you may find Chapter 12 of the their normal bonding patterns! Grade 0.5pt per structure Structures that have the san E DIFFERENT line structures that have a molecular formula e ch McMurry lecture text helpful). Make sure all atoms are following Structure 1 Structure 2 Structure 3 Question 2: How many tetrahedral carbon atoms...
EO 3- resonance structures, formal charges, stability
1. Draw ONE possible significant additional resonance structure for each of the following ions. Use curved arrows to show the movement of electrons that creates each new resonance structure. (Hint: lone pairs are not shown. Start by drawing in all one pairs, and include all lone pairs and formal charges in your additional resonance structure.) Page 1 of 3 2. For each structure, draw the resonance structure that is indicated by the curved...
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