For the unimolecular isomerization of cyclopropane to propylene, values of kuni versus initial pressure P0 at 470°C are
P0/torr | 110 | 211 | 388 | 760 |
105kuni/s−1 | 9.58 | 10.4 | 10.8 | 11.1 |
Take the reciprocal of Eq. (16.85) and plot these data in a way that gives a straight line. From the slope and intercept, evaluate kuni,P=∞ and the Lindemann parameters k1 and k−1/k2.
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