For the gas-phase reaction 2NO2 + F2 → 2NO2F, the rate constant k is 38 dm3 mol−1 s−1 at 27°C. The reaction is first- order in NO2 and first-order in F2. (a) Calculate the number of moles of NO2, F2, and NO2F present after 10.0 s if 2.00 mol of NO2 is mixed with 3.00 mol of F2 in a 400-dm3 vessel at 27°C. (b) For the system of (a), calculate the initial reaction rate and the rate after 10.0 s.
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