For the reaction A + B → C + D, a run with [A]0 = 400 mmol dm−3 and [B]0 = 0.400 mmol dm−3 gave the following data (where c° nu≡ 1 mol/dm3):
t/s | 0 | 120 | 240 | 360 | ∞ |
104[C]/c° | 0 | 2.00 | 3.00 | 3.50 | 4.00 |
and a run with [A]0 = 0.400 mmol dm−3 and [B]0 = 1000 mmol dm−3 gave
10 −3 t/s | 0 | 69 | 208 | 485 | ∞ |
104[C]/c° | 0 | 2.00 | 3.00 | 3.50 | 4.00 |
Find the rate law and the rate constant. The numbers have been chosen to make determination of the orders simple.
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