For the reaction OCl− + I− → OI− + Cl− in aqueous solution at 25°C, initial rates r0 as a function of initial concentrations (where c° = 1 mol/dm3) are:
103[ClO−]/c° | 4.00 | 2.00 | 2.00 | 2.00 |
103[I−]/c° | 2.00 | 4.00 | 2.00 | 2.00 |
103[OH−]/c° | 1000 | 1000 | 1000 | 250 |
103r0/(c° s−1) | 0.48 | 0.50 | 0.24 | 0.94 |
(a) Find the rate law and the rate constant. (b) Devise a mechanism consistent with the observed rate law.
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