Problem

The reaction n-C3H7Br + S2O32− → C3H7S2O− + Br− in aqueous solution is first order in C3H7...

The reaction n-C3H7Br + S2O32− → C3H7S2O− + Br− in aqueous solution is first order in C3H7Br and first-order in , the following data were obtained (where c° ≡ 1 mol/dm3 and 1 ks = 103 s):

103[S2O32−]/c°	96.6	90.4	86.3	76.6	66.8
t/ks	0	1.110	2.010	5.052	11.232

The initial C3H7Br concentration was 39.5 mmol/dm3. Find the rate constant using a graphical method.

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Solutions For Problems in Chapter 16

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The reaction n-C3H7Br + S2O32− → C3H7S2O− + Br− in aqueous solution is first order in C3H7...

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