Let Ea be the activation energy for the rate constant k in (16.95). (a) Relate Ea to Ea,1, Ea,−1, and Ea,2. (b) Measurement of k(T) gives Ea = 40.6 kcal/mol and A = 1.6 × 1011 dm3/2 mol−1/2 s−1. Use data in the Appendix to evaluate Ea,2 and find an expression for the elementary rate constant k2 as a function of T.
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